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5.3.4 Mass Analysis by Ion Cyclotron Resonance

Ions moving in a magnetic field travel with a curved trajectory. If the ions are initially traveling perpendicular to the magnetic field, the trajectory is actually a circle. If the field is strong enough, the ions can be trapped in this circular trajectory within the field. Such an experimental apparatus is called an ion cyclotron. Plates are placed near the radius of trajectory; as packets of ions pass the plates, they induce a charge on those plates. This creates a time dependent signal, with the signal large when the packets are close to the plate and small when they are far. The signal actually varies as a sine wave with the same period of oscillation as the ion packets in their circular trajector.

To collect the mass spectrum, a radio frequency pulse is focused on the ions. This causes the trajectory radius to expand; after the pulse, decay to the original trajectory radius is mass dependent. These time dependent decays cause more complicated waveforms to be induced on the plates. A Fourier Transform (as is used in FT-IR) is applied to the time dependent signal and produces the mass spectrum. Such Ion Cyclotron Resonance (ICR) instruments have produced the highest mass resolution of any mass selection technique. The mass of two electrons (much, much less than the mass of the lightest atom, H) can be resolved. Advances in this technique are leading to isomer resolution where the 'mass difference' is the relativistic (using $E=mc^{2}$) energy difference due to the different heats of formation.

ICR instruments are very expensive and used for research. The are not generally found in production analytical laboratories.


next up previous contents
Next: 5.3.5 Tandem and Hybrid Up: 5.3 Mass Analysis Previous: 5.3.3 Mass Analysis by   Contents
John S. Riley, DSB Scientific Consulting